Wednesday, 5 March 2025

Polyarylamide (PARA; MXD-6) and Recycling: How much regrind is possible?

Hello and welcome to a new post in which we discuss the usage of regrind when processing the high-performance Polyarylamide (PARA; MXD-6).


Recycling Process:

Polyarylamide regrind (sprues, runners, etc.), containing reinforcements such as glass fibers, can be recycled with virgin PARA compound. Important is to exclude any contamination such as oil, release agents, and other additives.

Impact on Mechanical Properties and Color Variation:

Several studies and experiments have shown [1] that a split of 70/30 (70 wt% virgin PARA / 30 wt% regrind) is preferred. The compound used in each cycle is 70% virgin compound (containing 50 wt% glass fibers) mixed with 30% regrind from the preceding cycle. Very little change is observed in these mechanical properties (tensile strength, elongation at break) after recycling. Successive recyclings may cause a slight change in color. 

Recommendations:

Important is to confirm the recycling rate experimentally to ensure the finished part meets specifications. Also, drying the regrind prior to injection unless ground and reinjected at the press. Mark parts to facilitate after-use recycling (check out the part marking codes here).

Thanks for reading and #findoutaboutplastics

Greetings

Literature: 
[1] https://content.solvay.com/ixef-para-processing-guide



Tuesday, 4 March 2025

Become a Master in Polymer Material Selection - Learn & Apply the “6 POMS” Skills

Hello and welcome to a new blog post. Over the course of my career as a polymer engineer, I have sought to delineate the requisite skills for effective polymer material selection. Through discussions with polymer engineers responsible for successful plastic product development over the past decade, it has become evident that proficiency in six distinct areas is consistently demonstrated. These individuals not only possess comprehensive knowledge but also apply it rigorously across multiple product development cycles. Through iterative refinement and detailed analysis, these six areas have been systematically mapped. Consequently, I have formalized these competencies into what I now refer to as the "6 POMS" skills (Figure 1).

The 6 Polymer Material Selection Skills

Figure 1: Overview of the 6 POMS skills helping to become a Master in polymer material selection [1].

Let us discuss each of the 6 P's:

P- Properties: Understanding key polymer properties 

To effectively select polymers for specific applications, a thorough understanding of their key properties is essential. This includes familiarity with polymer structure properties like morphology, molecular weight, and thermal transitions. Knowledge of mechanical properties such as tensile, flexural, and impact strength, stiffness, and elongation is crucial. Additionally, a grasp of thermal properties, including glass transition temperature (Tg), melting temperature (Tm), and heat resistance, is necessary. The ability to assess chemical resistance to acids, bases, solvents, and oxidation is also vital. Furthermore, awareness of both long-term and short-term properties and their relationship to application requirements is paramount. Finally, understanding multi-point property data and its relevance to application needs ensures optimal material selection.

P - Part Design: Defining Application Requirements for Plastic Part Design 

The success of a plastic part depends heavily on its ability to meet the specific demands of its intended application. To ensure this, a structured approach to defining requirements is essential. This involves using tools like requirement checklists and methodologies such as the FLERP approach (Function, Loading conditions, Environmental Factors, Regulatory requirements, and Processing requirements).

A crucial aspect of this process is the ability to write clear and concise product specifications. This requires a deep understanding of the part's true functions, load cases, and material requirements. Additionally, it is important to consider the data needed for plastic part design, including material properties, processing parameters, and environmental factors.

Finally, cost considerations should be integrated throughout the design process. This involves evaluating material and manufacturing costs to optimize the overall design and ensure economic viability. By following these steps, engineers can effectively define application requirements and design plastic parts that meet the needs of their intended use.

P - Polymer material values: Translating application requirements to qualitative and quantitative material values

Translating plastic application requirements into actionable material values is a critical step in the selection process. This involves understanding how qualitative and quantitative application needs correspond to specific material properties. A systematic approach, such as listing all application requirements and their translated material values in a dedicated system or sheet, significantly enhances the selection process by providing a clear and organized framework for evaluation.

P - Process: Polymer material selection process

The process of selecting polymer materials involves several key considerations. It's important to determine if a structured, step-by-step approach is currently in place. Utilizing online databases like CAMPUS or Omnexus for material identification is common practice. A fundamental understanding of how to interpret technical datasheets for plastics is also crucial. Furthermore, the selection process should involve a degree of critical thinking, including challenging the use of established materials and exploring alternative options. Questioning the rationale behind choosing specific resins and ensuring they align with actual requirements is vital. Finally, the use of decision-making tools can significantly facilitate the selection of appropriate plastics.

P - Performance: Evaluation of material and part performance

Evaluating plastic material and part performance requires a comprehensive approach. Utilizing CAE tools, like injection mould filling simulation and FEA, enables virtual testing and optimization of plastic parts. Familiarity with standard ISO tests, such as tensile tests, is essential for quantifying material properties. Physical prototyping plays a critical role in verifying material and part functionality. Ultimately, experience in testing both material and part performance is crucial to confirm the suitability of the chosen plastic for its intended application.

P - Plastic supplier: Selection of material and supplier

The selection of plastic materials and suppliers involves active engagement and collaboration. Regularly discussing application requirements with polymer application engineers is crucial for ensuring material suitability. Direct contact with material suppliers to obtain samples supports the selection process by allowing for physical testing and evaluation. Seeking recommendations from plastics experts and material suppliers on new material developments ensures access to the latest advancements and potential solutions.

How to train the 6 POMS skills and become a master in polymer material selection? 

Start by taking my new developed Polymer Material Selection test and discover your polymer material selection score. Assess where you are currently ranking at the different POMS skills and increase your ability to select plastics better. It is a simple test which consists of 26 Yes/No questions. After submitting, you will receive a report containing your overall POMS score, the detailed score and recommendations for improvements.

I invite you to take the test, get your POMS-score and review the suggested improvements.

Thanks for reading & #findoutaboutplastics!

Greetings, 

Herwig 

New to my Find Out About Plastics Blog - check out the start here section


Literature: 

[1] https://www.polymermaterialselection.com/poms-score

[2] https://www.amazon.de/-/en/Polymer-Material-Selection-practical-systematic/dp/B0BSWM6BPD


Thursday, 20 February 2025

📚 My new book, "Pumping Plastics 2024," is out now! Available as Paperback Worldwide on Amazon!

Dear community, I'm thrilled to announce the release of "Pumping Plastics 2024," featuring guest interviews with leading material manufacturers and medical-grade plastics consultants. Explore the latest advancements in high-performance polyamides (PARA), material selection, polymer design properties, and more. 

My new book, "Pumping Plastics 2024," is out now!

This book, weighting 135 pages, contains all the posts published on my FindOutAboutPlastics.com blog in 2024. It is part of my "Pumping Plastics" book series. 

For instances, this include topics such as:

  • Guest interviews with innovative material manufacturers and medical grade
  • plastics consulting
  • High performance polyamides such as Polyarylamides (PARA)
  • Polymer design properties and multi-point design data
  • Polymer material selection examples
As a bonus, the first chapter of my first book "Polymer Material Selection" is included.

Pumping Plastics 2024 by Herwig Juster is part of the "Pumping Plastics" book series. 

Level up your materials knowledge – grab your copy here and stay ahead of the curve!

Thanks & #findoutaboutplastics

Greetings,

Herwig Juster

#PumpingPlastics2024


Monday, 17 February 2025

Injection Moulding of Polyphenylene sulfide (PPS) - The Key to High Crystallinity and Performance

Hello and welcome to a new post in which we discuss the importance of mould temperature for achieving optimal crystallinity and performance in polyphenylene sulfide (PPS) moulded parts.  

Why is mould surface temperature critical with PPS?

The high-performance polymer PPS is a semi-crystalline polymer and its backbone consists of aromatic rings (phenylene groups) linked by sulfide bridges. It has a glass transition temperature of 88°C, melting temperature of 282°C and a processing temperature of 320°C. It combines high heat resistance (UL 746B exceeding 200°C), with high chemical resistance and mechanical strength at an economical price range.  As a high temperature plastics, also attention to proper processing, especially injection moulding needs to be given. Achieving the optimal level of crystallinity of PPS parts is important. 

Crystallinity significantly impacts the part's performance and stability, and even cooling is essential for high-quality mouldings. Mould surface temperature for PPS should be between 135° and 150°C in order to obtain high levels of crystallinity (maximum crystallinity levels of PPS: 55%).

Injection mould temperature settings for PPS

There is the "hot mould" and "cold mould" approach.  "Hot mould" temperatures (above 135°C) are preferred for precision parts as they promote crystallization, resulting in the best overall appearance, thermal stability, and dimensional stability.  "Cold mould" temperatures (below 88°C), on the other hand, produce amorphous parts with a mottled/grainy surface appearance. While cold moulds offer some advantages in physical properties and less shrinkage directly out of the mould, hot moulds are generally favored for achieving the best balance of properties, especially in precision applications.

Important are suitable cooling methods, and it is recommended to use circulation-type systems using hot oil or pressurized water.  If heater cartridges are used, they should have a minimum capacity of 1 kW per cartridge. 

Differential Scanning Calorimetry (DSC) can assess crystallinity in an effective way.

After moulding the PPS part, we can use the DSC to check if the part was fully crystallized and as a consequence, all important properties such as thermal and chemical stability, as well as dimension stability are fully developed. Figure 1 shows the results of two DSC curves. The upper curve shows a not fully crystallized PPS, having a so-called cold crystallisation peak at 114°C (exothermal) and a melting peak at 282°C. The lower curve shows a fully crystallised PPS part having only a melting peak at 282°C. 

Figure 1: Example comparison DSC curve of a not fully and fully crystallized Polyphenylene sulfide (PPS) moulded part. 

Conclusion

In essence, the careful control and selection of mould temperature (135-150°C), along with appropriate cooling methods, are crucial for optimizing the crystallinity and ultimately the performance of PPS moulded parts.

If you need support in moulding high-performance polymers such as PPS and PEEK, you can reach out to me here .

Learn more about high performance polymers such as PPS in my series “High Performance Thermoplastics Selection” .

Thanks for reading and #findoutaboutplastics

Greetings

Literature: 
[1] https://www.syensqo.com/en/brands/ryton-pps
[2] https://analyzing-testing.netzsch.com/de/produkte/dynamische-differenzkalorimetrie-dsc-differenz-thermoanalyse-dta
[3] https://www.solvay.com/sites/g/files/srpend221/files/2018-08/Ryton-PPS-Mold-Temperature_EN-v1.0_0.pdf